MIT 5.61 Physical Chemistry, Fall 2017 (English)

   Monday, December 09, 2024   

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MIT 5.61 Physical Chemistry, Fall 2017 By Lecture Notes together!

Lecture 1: 1. Quantum Mechanics—Historical Background, Photoelectric Effect, Compton Scattering

Lecture 2: 2. Wave Nature of the Electron and the Internal Structure of an Atom

Lecture 3: 3. Two-Slit Experiment; Quantum Weirdness

Lecture 4: 4. Classical Wave Equation and Separation of Variables

Lecture 5: 5. Quantum Mechanics: Free Particle and Particle in 1D Box

Lecture 6: 6. 3-D Box and QM Separation of Variables

Lecture 7: 7. Classical Mechanical Harmonic Oscillator

Lecture 8: 8. Quantum Mechanical Harmonic Oscillator

Lecture 9: 9. The Harmonic Oscillator: Creation and Annihilation Operators

Lecture 10: 10. The Time-Dependent Schrödinger Equation

Lecture 11: 11. Wavepacket Dynamics for Harmonic Oscillator and PIB

Lecture 12: 12. Catch Up and Review & PostulatesL3.4 Degeneracy resolved to second order (continued)

Lecture 13: 13. From Hij Integrals to H Matrices I

Lecture 14: 14. From Hij Integrals to H Matrices II

Lecture 15: 15. Non-Degenerate Perturbation Theory I

Lecture 16: 16. Non-Degenerate Perturbation Theory II: HO using a,a†

Lecture 17: 17. Rigid Rotor I; Orbital Angular Momentum

Lecture 18: 18. Rigid Rotor II. Derivation by Commutation Rules

Lecture 19: 19. Spectroscopy: Probing Molecules with Light

Lecture 20: 20. Hydrogen Atom I

Lecture 21: 21. Hydrogen Atom II; Rydberg States

Lecture 22: 22. Helium Atom

Lecture 23: 23. Many-Electron Atoms

Lecture 24: 24. Molecular Orbital Theory I; Variational Principle and Matrix Mechanics

Lecture 25: 25. Molecular Orbital Theory II; H2+, A2, AB Diatomics

Lecture 26: 26. Qualitative MO Theory: Hückel

Lecture 27: 27. Non-Degenerate Perturbation Theory III

Lecture 28: 28. Modern Electronic Structure Theory: Basis Sets

Lecture 29: 29. Modern Electronic Structure Theory: Electronic Correlation

Lecture 30: 30. Time-Dependent Perturbation Theory I: H is Time-Independent, Zewail Wavepacket.

Lecture 31: 31. Time-Dependent Perturbation Theory II: H is Time-Dependent: Two-Level Problem

Lecture 32: 32. Intermolecular Interactions by Non-Degenerate Perturbation Theory

Lecture 33: 33. Electronic Spectroscopy: Franck-Condon

Lecture 34: 34. Electronic Spectroscopy and Photochemistry

Lecture 35: 35. Delta-Functions, Eigen-Functions of X, Discrete Variable Representation

Lecture 36: 36. Time Dependence of Two-Level Systems: Density Matrix, Rotating Wave Approximation